Formation of Enol Ethers by Radical Decarboxylation of α-Alkoxy β-Phenylthio Acids.
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Palanivel, A., Mubeen, S., Warner, T., Ahmed, N., & Clive, D. L. J. (2019). Formation of Enol Ethers by Radical Decarboxylation of α-Alkoxy β-Phenylthio Acids. Journal of Organic Chemistry, 84(19), 12542–12552. https://doi-org.login.ezproxy.library.ualberta.ca/10.1021/acs.joc.9b02042
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Abstract
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Enol ethers are formed by radical decarboxylation of -alkoxy -phenylthio acids via the
corresponding Barton esters. The phenylthio acids were usually made by the known
regioselective reaction of ,-epoxy acids with PhSH in the presence of InCl3, followed by Oalkylation
of the resulting alcohol. In one case thiol addition to an ,-unsaturated ethoxymethyl
ester was used.
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http://purl.org/coar/resource_type/c_6501 http://purl.org/coar/version/c_b1a7d7d4d402bcce http://purl.org/coar/version/c_71e4c1898caa6e32
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This document is the Accepted Manuscript version of a Published Work that appeared in final form in Journal of Organic Chemistry, copyright © 2019 American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.joc.9b02042.
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en