A ruthenium-carbamato-complex derived from a siloxylated amine and carbon dioxide for the oxidative a-cyanation of aromatic and cyclic tertiary amines
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The ruthenium carbamate complex derived from 3-trimethoxysilyl-1-
propyl amine and carbon dioxide was found to be a novel catalyst for
the oxidative cyanation of aromatic and cyclic tertiary amines to
corresponding a-amino nitriles in high to excellent yields by using
hydrogen peroxide and molecular oxygen as enviro-economic
oxidants. The developed protocol suggested an efficient alternative
for recycling carbon dioxide.
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http://purl.org/coar/resource_type/c_6501 http://purl.org/coar/version/c_970fb48d4fbd8a85
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en