Edge-confined under-coordinated Cu atoms on Ru nanosheets enable efficient CH4 activation
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In this issue of Chem Catalysis, Jinchang Fan et al. demonstrate that Cu atoms confined in ultrathin 2D metallic Ru nanosheets (Ru11Cu NSs) favor bi-coordinated adsorption of O∗ species to reduce the activation energy barrier for a facile C–H bond cleavage to C1 oxygenates (CH3OOH and CH3OH) with 99% selectivity.
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http://purl.org/coar/resource_type/c_6501 http://purl.org/coar/version/c_970fb48d4fbd8a85
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en